A Multi-iron System Capable of Rapid N2 Formation and N2 Cleavage
نویسندگان
چکیده
منابع مشابه
A Multi-iron System Capable of Rapid N2 Formation and N2 Cleavage
The six-electron oxidation of two nitrides to N2 is a key step of ammonia synthesis and decomposition reactions on surfaces. In molecular complexes, nitride coupling has been observed with terminal nitrides, but not with bridging nitride complexes that more closely resemble catalytically important surface species. Further, nitride coupling has not been reported in systems where the nitrides are...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2014
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja505193z